What is 1,4-Dioxane?

1,4-dioxane is a synthetic industrial chemical that mixes completely in water. It persists for a very long time in the environment and is associated with many health risks. Manufacturers often use it as a solvent to create other chemicals like those found in cosmetics, detergents, shampoos, paint strippers, glues, pesticides, medicines and foods. It is also used in the manufacturing of pharmaceuticals and is a byproduct in the production of certain plastic containers.

1,4-Dioxane and your health

The EPA suspects 1,4-dioxane may cause cancer when people are exposed to it through air, water, or by skin contact over time. Short-term exposure effects include eye and nose irritation. Other long-term exposure effects may include liver and kidney damage.

1,4-Dioxane and the Huron River watershed

A large 1,4-dioxane plume is spreading beneath western Ann Arbor and Scio Township due to decades of pollution from the Gelman Sciences (now Pall Corp., a division of Danaher Corp.) facility on Wagner Road. A plume is an area underground where the dioxane is moving through soil or water. The plume exists because dioxane does not stick to soil particles, so it can move from soil into groundwater and eventually reach surface water. The plume likely originated around 1966 when Gelman began using dioxane to manufacture various medical and scientific products.

Dioxane Plume Map Washtenaw
1,4-Dioxane Plume map, Washtenaw County, Michigan. Credit: Washtenaw County Health Department, November 2019

In 1984, University of Michigan Public Health graduate student Dan Bicknell discovered 1,4-dioxane in Third Sister Lake in west Ann Arbor near the Gelman property. By 1985, the Washtenaw County Health Board found the presence of dioxane in 30 water supply wells north of the Gelman property. The state initially sued Gelman in 1988, leading to a 1992 Circuit Court consent judgement, in which Gelman agreed to pay the state over $1 million in damages and begin a $4 million cleanup project.

Gelman has spent years conducting pump-and-treat remediation under court orders, gradually extracting contaminated water from the ground and treating it to remove dioxane the company once dumped into the environment. The treated water with lower levels of dioxane is then discharged to a tributary of Honey Creek, which flows to the Huron River.

Between 1995 and 2000, then Governor Engler and the Michigan State Legislature took a series of actions that increased the allowed level of 1,4-dioxane in residential groundwater from 3 ppb (parts per billion) to 85 ppb―much higher than the EPA’s guideline of 0.35 ppb.

In 2016 traces of 1,4-dioxane were found beneath Waterworks Park in west Ann Arbor. In response, the Michigan Department of Environmental Quality (now the Michigan Department of Environment, Great Lakes and Energy or EGLE) set an emergency standard of 7.2 ppb allowed in residential drinking water. The emergency rule was made permanent in 2017. That same year, HRWC, the City of Ann Arbor, Scio Township and Washtenaw County joined the state’s lawsuit against Gelman to negotiate for a stronger clean up.

In 2019 and 2020, elected officials from the City of Ann Arbor, Scio Township, Ann Arbor Township, and Washtenaw County held forums to discuss the option of pursuing Superfund designation for the dioxane plume , which would place the Environmental Protection Agency (EPA) in charge of cleanup activities at the site instead of the State of Michigan. HRWC informed these discussions and remains committed to the legal negotiations as the current best way forward. No decision has yet been made by the affected communities to pursue Superfund status.

Scientific monitoring shows that, despite prolonged attempts to mitigate the spread of the of the dioxane plume, it continues to grow.

What HRWC is doing

To protect the Huron River, we have taken steps to limit the spread the dioxane plume. In 2016, HRWC the City of Ann Arbor, and Washtenaw County joined the state’s lawsuit against Gelman. HRWC’s motivation for joining the lawsuit was our belief that the river needed a strong advocate and our concern for impacts to the river stemming from a lack of cleanup action. Former Executive Director Laura Rubin said “the city will represent concerns about groundwater contamination and the county’s focus will be well water contamination. But we feel the interests of the river are at risk and that nobody’s representing those.” The dioxane could affect fish and other aquatic life, as well as people, if it gets to our streams or the Huron River itself.

HRWC is committed to securing a new court order for a better cleanup of the dioxane plume.

HRWC supports proposed 1,4-Dioxane cleanup in Gelman case/lawsuit

Gelman 1,4-Dioxane Litigation

On August 31, 2020, the Washtenaw County Circuit Court partially lifted the confidentiality restriction against disclosure of the negotiations between Gelman Sciences, the State of Michigan and the intervenors (City of Ann Arbor, Scio Township, Washtenaw County and its Health Department, and HRWC). The proposed settlement documents that resulted from these negotiations are now public and can be viewed via a document repository webpage. The proposed documents, which still need to be voted on by the intervenors, include the Fourth Amendment to the 1992 Consent Judgment, Dismissal Order, and Settlement Agreements. Other documents and a set of videos that help with an understanding of the proposed settlement documents are also available on the repository webpage.

There will be opportunities for public input. It is anticipated that one or more work sessions could be scheduled of Ann Arbor City Council, Washtenaw County Board, and the Scio Township Board. Future public meetings and engagement will be scheduled and announced by each of the respective local governments.​

Quick Links:

Gelman Proposed Settlement Documents Repository Page, includes Consent Judgment proposed fourth amendment and related documents

Gelman 1,4-Dioxane Litigation Page, includes historic timeline and answers to frequently asked questions

News Release, issued August 31, 2020

Upcoming Public Meetings

September 14, 2020, 6-8pm, EGLE public comment meeting. Written public comments accepted until September 21.​

September 24, 2020, 6:30pm, Q&A and public hearing with Washtenaw County Board of Commissioners, Ann Arbor City Council, Congresswoman Dingell and Intervenors’ expert Dr. Lawrence Lemke. Submit questions by September 18. Written comments are welcome at any time as are oral comments on September 24.

What you can do

If you are using a well system, you should have your water tested regularly. If you live directly over the plume or near the edge of it, EGLE should have contacted you about doing testing, all you must do is allow it. If you have not been contacted and your well water is not being tested, please contact Jennifer Conn at Washtenaw County Health Department (734) 222-3855 or Dan Hamel at EGLE (517) 780-7832.

If you are connected to the City of Ann Arbor’s water supply, you can read the latest Water Quality Report to find out more about 1,4-dioxane levels.

If you would like to test your water, you are responsible for any cost. See Testing Your Drinking Water for 1,4-Dioxane. There are three laboratories located near our community that you can use.

Arbor Technical Services
290 S. Wagner
Ann Arbor, MI 48103
(734) 995-0995
Info@AnnArborTechnicalServices.com

Brighton Analytical
2105 Pless Drive
Brighton, MI 48114
(810) 229-7575
Bai-brighton@sbcglobal.net

Michigan Department of Environment, Great Lakes, and Energy
Drinking Water Laboratory
P.O. Box 30270
Lansing, MI 48909
(517) 335-8184

Resources

For more detailed background information or the technical details of the current plume mitigation efforts, please consult the following resources:

Environmental Protection Agency: 1,4-Dioxane Technical Fact Sheet

Agency for Toxic Substances and Disease Registry: Toxic Substances Portal – 1,4-Dioxane

State of Michigan water sampling guide.

Ann Arbor 1,4-Dioxane Fact Sheet

Washtenaw County; 1,4-Dioxane Groundwater Contamination Fact Sheet

Coalition for Action on Remediation of Dioxane (CARD) Website

Stay Tuned for Updates

This is an ongoing issue for the Huron River watershed. You can get free HRWC updates by signing up for our emails.



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3/3/20| With dioxane legal case pending, Ann Arbor again delays Superfund action

Ann Arbor City Council voted 8-1 to delay consideration of a Superfund resolution calling for Environmental Protection Agency intervention, giving more time for parties to negotiate legal settlement.

2/4/20| Ann Arbor officials hopeful after meeting with judge in Gelman plume case

Ann Arbor, Washtenaw County and Scio Township officials, along with the Huron River Watershed Council and the state, are still trying to get a new cleanup plan in place in the form of a revised Circuit Court consent judgement. They say they’re nearing a decision point after months of confidential settlement negotiations with polluter Gelman Sciences,

1/17/20| ‘We’re really, really slow,’ EPA tells local officials seeking pollution cleanup

EPA tells local officials seeking pollution cleanup “We’re really, really slow,” explaining it could take decades. EPA and Michigan Department of Environment, Great Lakes and Energy representatives fielded questions about the Superfund cleanup process at a public forum for local officials and residents hosted by U.S. Rep. Debbie Dingell,

6/8/19| Officials set timeline for seeking Superfund cleanup of Ann Arbor dioxane plume

A joint session of the City Council, Washtenaw County Board of Commissioners, and Scio and Ann Arbor township boards met to discuss petitioning the U.S. Environmental Protection Agency for Superfund designation of the Gelman dioxane plume. The plume has been spreading through the area’s groundwater for decades. A Superfund designation would allow the EPA to clean up contaminated sites. It also forces the parties responsible for the contamination to either perform cleanups or reimburse the government for EPA-led cleanup work.

5/23/19| Next steps for Gelman dioxane plume topic of upcoming meetings

1,4-dioxane will be the focus of a May 28 and June 6 meeting with citizens, local and federal officials. The joint discussion will help show a united front against the issue. All parties affected are seeking a better cleanup and monitoring after years of limited pump –and-treat remediation that has allowed the pollution to spread for miles, inching toward the Huron River.

4/29/19| Scientists propose “biosparging” to clean up 1,4-dioxane pollution near Lansing

A new method of removing toxins from an underground plume known as “biosparging” turns heads. Biosparging would remove pollution by injecting air into groundwater. This will encourage bacteria to consume toxins like 1,4-dioxane.

3/14/19| Ann Arbor officials say no dioxane detected in latest drinking water tests

After Barton Pond tested positive for small traces of 1,4-dioxane in February the latest tests of samples collected this month showed no dioxane in either the intake water or the treated water. The water quality team at the City of Ann Arbor will continue to send water sample to an independent lab each month to test for 1,4-dioxane and the results will be posted on the city’s website.

3/1/19| Dioxane detected in Ann Arbor drinking water from Barton Pond for first time

A recent round of lab tests at Ann Arbor’s water treatment plant showed 1,4-dioxane in the city’s surface water supply and in the finished drinking water. Results estimated concentrations of 0.061 parts per billion at the city’s intake in Barton Pond and 0.030 ppb in the treated drinking water. The city maintains the water is safe to drink, with dioxane levels equal to about one drop of water in an Olympic-sized swimming pool.

1/30/19| Michigan Supreme Court rejects polluter’s appeal in Ann Arbor dioxane case

The state’s highest court has rejected Gelman Science’s appeal seeking to overturn a local judge’s rulings, which means local parties can continue to fight in court for a better cleanup. The company is against allowing the City of Ann Arbor, Scio Township, Washtenaw County and the Huron River Watershed Council to have seats at the negotiating table as attempts are made to come up with a new plan of attack for addressing the plume.

11/28/18| Higher dioxane levels in West Park increase need for water testing

Water samples taken from the storm sewers at West Park in Ann Arbor reveal an increase in the levels of 1,4-dioxane. In response to the increase in dioxane contamination, the Michigan Department of Environmental Quality has confirmed plans for further dioxane testing in Ann Arbor.

12/19/16| Other groups join lawsuit to cleanup Ann Arbor’s 1,4 dioxane plume

A judge allowed the Huron River Watershed Council to become one of the plaintiffs in a lawsuit to force a cleanup of Ann Arbor’s contaminated water. HRWC is joining the lawsuit because it feels the river needs a specific voice and advocate for the harms dioxane potentially bring to its wildlife and residents that depend on the Huron for their drinking water.

12/7/16| Huron River Watershed Council and county take legal action on dioxane

Washtenaw County and the Huron River Watershed Council are joining the City of Ann Arbor in taking legal action in hopes of getting a better cleanup of the Gelman dioxane plume. The case is expected to be reopened in Washtenaw County Circuit Court on Dec. 15. If the judge agrees, the city, the county and HRWC could join the state as co-plaintiffs in the case against polluter Gelman Sciences, the defendant.

11/2/16| Ann Arbor City Council votes to intervene In 1,4-dioxane plume court case

The Ann Arbor City Council passed a resolution to direct city officials to seek permission from the court to intervene in a lawsuit over groundwater contamination in and around the city.